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TheimportanceofInterfacialandColloidScienceacrossthespectrumfromindustrialmanufacturingtoenergydevelopmenttobiomedicalresearchtoeverydayactivitiesfromcookingtocleaningisbeyonddispute.Still，itistobefoundinrelativelyfewcourses，particularlyrequiredcourses，inscienceandengineeringcurriculainourcollegesanduniversities.Moreoften，itisthatchapterinone''sphysicsorchemistrytextthatisneverassigned.Theearlystirringsofashiftincurriculatoincludethismaterialisunderway，however，particularlyasnewtoolsandinsightsarerapidlyemerginganditisrecognizedasthebridgetotheneweraofnanoscienceandnanotechnology.Thistextisaddressedtobothundergraduateandgraduatestudentsinscienceandengineeringprogramsaswellastopractitioners，althoughevenhighschoolstudentsshouldenjoypartsofit.Itsevolvingversionshavebeenused，Ibelievesuccessfully，inbothundergraduateandgraduateelectivecoursesinChemicalEngineeringatthe?UniversityofWashington，aswellasinavarietyofindustrialshortcoursessincethemid1980''s.ItisnowusedasthetextforacourseinInterfacialandColloidScience，withasignificantlaboratorycomponent，thathasjustbecomerequiredforundergraduateChemicalEngineeringstudentsatWashingtonastheDepartmentembracesashifttowardmolecularengineeringandnanoscience.
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Preface
Ⅰ.INTRODUCTION
A.Interfaces
B.Colloids
C.Thebridgetonanoscience
1.Whatis"nanoscience?"
2.Nanostructuresandassemblies
3.Genericnanoscience
4.Newtoolsofgenericnanoscience
5.Theplan
Ⅱ.FLUIDINTERFACESANDCAPILLARITY
A.Fluidinterfaces:Young''smembranemodel
1.Thethinnessofinterfaces
2.Definitionofsurfacetension
B.Thesurfacetensionofliquids
1.Pureliquids
2.Temperaturedependenceofsurfacetension
3.Surfacetensionofsolutions
C.Intermolecularforcesandtheoriginofsurfacetension
1.VanderWaalsforces
2.Surfacetensionas"unbalanced"intermolecularforces;theHamakerconstant
3.Pressuredeficitintheinterfaciallayer;Bakker''sequation
4.Componentsofthesurfacetension
D.Interfacialtension
1.Experimentalinterfacialtension
2.Combiningrulesforinterfacialtension
E.Dynamicsurfacetension
F.Capillaryhydrostatics:theYoung-LaplaceEquation
1.Capillarypressure:pressurejumpacrossacurvedfluidinterface
2.Thecurvatureofasurface
3.DerivationoftheYoung-Laplaceequation
4.BoundaryconditionsfortheYoung-Laplaceequation
G.SomesolutionstotheYoung-Laplaceequation
1.Cylindricalsurfaces;meniscusagainstaflatplate
2.Axisymmetricandothersurfaces
3.NondimensionalizationoftheYoung-Laplaceequation;theBondnumber
4.Saddle-shapedsurfaces
H.Themeasurementofsurfaceandinterfacialtension
1.Geometricvs.forcemethods
2.Capillaryrise
3.Sessiledropandpendantdrop
4.DuNotiyringdetachment
5.Wilhelmyslide
6.Langmuirfilmbalance1.Dropweight（orvolume）
8.Maximumbubblepressureanddynamicsurfacetension
9.Thepulsatingbubble"surfactometer"
10.Elliptical（vibrating）jet
11.Contractingcircularjet
12.Problemswithinterfacialtensionmeasurement
13.Spinningdropmethod
I.Forcesonsolidsincontactwithliquids:capillaryinteractions
1.Liquidbridges
2.Sharedmenisci
J.Effectofcurvatureontheequilibriumpropertiesofbulkliquids:theKelvinEffect
1.Thevaporpressureofsmalldropletsandliquidsinpores
2.Theeffectofcurvatureonboilingpoint
3.Capillarycondensation
4.NucleationK.Thinliquidfilms
1.Disjoiningpressureanditsmeasurement
2.Themolecularoriginofdisjoiningpressure
3.Thedisjoiningpressureisotherm
4.TheaugmentedYoung-Laplaceequation
SOMEFUNTHINGSTODO:CHAPTER2
Ⅲ.THERMODYNAMICSOFINTERFACIALSYSTEMS
A.Thethermodynamicsofsimplebulksystems
1.Thermodynamicconcepts
2.Thesimplecompressiblesystem
B.Thesimplecapillarysystem
1.Theworkofextension
2.Heateffects;abstractproperties;definitionofboundarytension
C.Extensiontofluid-solidinterfacialsystems
1.Theworkofareaextensioninfluid-solidsystems
2.Compoundinterfacialsystems;Young''sequation
D.Multicomponentinterfacialsystems
1.TheGibbsdividingsurfaceandadsorption
……
Ⅵ.SOLID-LIQUIDINTERACTIONS
Ⅴ.COLLOIDALSYSTEMS:PHENOMENOLOGYANDCHARACTERIZATION
Ⅵ.ELECTRICALPROPERTIESOFINTERFACES
Ⅶ.INTERACTIONBETWEENCOLLOIDPARTICLES
Ⅷ.RHEOLOGYOFDISPERSIONS
Ⅸ.EMULSIONSANDFOAMS
Ⅹ.INTERFACIALHYDRODYNAMICS
Appendix1:EXERCISES
Appendix2:THETOPTEN
Appendix3:OTHERSOURCES
Index
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