《Green Catalytic Hydrogenation of Phthalate Plasticizers(增塑剂绿色催化技术)》在国内外文献调研和实验室研究基础上,从物质结构和分子水平上阐述邻苯类增塑剂分子结构改性的微观机制,阐明苯环改性和酯基调控的多相催化机理以及产物分离、产品应用的科学依据,以及国内外相关法律法规,为增塑剂行业实现转型发展、绿色发展提供有益借鉴。
目錄:
Contents1 Introduction 11.1 Background 11.2 Fundamentals of Plasticizers 61.2.1 Symbols and Abbreviations 61.2.2 Major Functions of Plasticizers 61.2.3 Major Performance-Determining Factors for Plasticizers 101.2.4 Mechanism for Plasticity Increase by Plasticizers 111.2.5 Property Requirements for Plasticizers 131.2.6 Inspection Standards for Plasticizers 181.2.7 Types of Plasticizers 181.3 Cyclohexane-1, 2-Dicarboxylate Plasticizers 221.4 Environmentally Friendly Plasticizers 251.5 Developmental Direction of Plasticizer Industry in China 261.6 Main Contents of This Book 27References 272 Foreign and Domestic Plasticizer Laws 332.1 Foreign Plasticizer Laws, Evolution 332.2 Domestic Plasticizer Laws and Evolution 332.3 Interpretations of Foreign and Domestic Plasticizer Laws 372.3.1 EU Bans 372.3.2 EU’s REACH Policy [1,2] 392.3.3 The EU’s RoHS [1,3] 402.3.4 USA’s CPSIA 422.3.5 Related Phthalate Laws in Other Countries 442.3.6 Domestic Laws [4–6] 442.4 Comparison and Trend of Plasticizer Laws for Food Contact Applications 472.4.1 Current Status 472.4.2 Chinese Laws and Regulations 472.4.3 EU’s Laws and Regulations 472.4.4 USA’s Laws and Regulations 482.5 Conclusion 48References 493 Current Status of Plasticizer Research 513.1 Foreign Research Status 513.1.1 Phthalate Hydrogenation Technology 513.1.2 Research on Toxicity of Phthalate Compounds 553.2 Domestic Research Status 553.2.1 Synthesis of DIBCH(1999)[9] 553.2.2 Synthesis of HHPA(2000)[10] 573.3 Di(2-Propylheptyl) Phthalate (2006) [13] 593.3.1 Physical Properties 593.3.2 Performance 603.4 Cyclohexane Dicarboxylate Plasticizers (2010)[14] 643.4.1 Preparation of Cyclohexane Dicarboxylate Plasticizers 653.4.2 Properties and Assessment of Cyclohexane Dicarboxylate Plasticizers 663.4.3 Application Examples of Formulation 713.4.4 Conclusion 723.5 Development Status of Plasticizers (2010, 2011) [18,19] 733.5.1 Status of Plasticizers in Foreign Countries 733.5.2 Status of Plasticizers in China 733.5.3 New Environmentally Friendly Plasticizers 753.5.4 Sustainable Development of Plasticizers in China 753.6 Diisononyl Cyclohexane-1,2-Dicarboxylate(2010,2014)[20,21] 763.6.1 Physical Properties 773.6.2 Production Routes of DINCH 773.6.3 Applications of DINCH 793.7 Environmentally Friendly Plasticizers 813.7.1 Di(2-Ethylhexyl) Cyclohexane-1,2-Dicarboxylate Plasticizer(2011)[22] 813.7.2 Research and Application Progress of Catalytic Synthesis of Environmentally Friendly Plasticizers(2012)[15] 833.7.3 Innovations and Applications of Green Plasticizers[97] 913.7.4 Technological Innovation and Market Dynamics of Green Plasticizers(2017)[98] 933.8 Hydrogenation of Dioctyl Phthalate (2012)[34] 943.9 Liquid-Phase Catalytic DOP Hydrogenation and Kinetics(2012)[50] 943.10 Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2013)[38,113,114] 973.11 Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2014–2015) 1003.11.1 Preparation of DOP Hydrogenation Catalyst(2014)[120] 1003.11.2 DEHP Hydrogenation Product Analysis Using GC-MC (2015)[42] 1003.12 Synthesis of DEHCH via Direct Esterification (2015)[121] 1033.13 Cable Industry’s Response to EU’s Newest Environmental Laws 1083.14 Applications of Environmentally Friendly Plasticizers in Disposable Gloves(2016)[127] 1083.15 Development and Application of Environmentally Friendly Polyester Plasticizers (2016)[128] 1093.16 How to Accurately Assess and Use Benzoate-Based Plasticizers?(2016)[129] 1103.17 Production Study of Environmentally Friendly DEHCH Plasticizer(2016)[130] 1133.18 Co-existing Opportunities and Challenges for DOP Market(2017)[115] 1153.19 Conclusion 117References 1224 Foreign and Domestic Inventions and Patents 1294.1 Foreign Inventions and Patents 1294.1.1 Hydrogenation Methods 1294.1.2 Esterification Methods 1334.2 Domestic Inventions and Patents 1344.2.1 A Catalyst for Hydrogenating Dimethyl Terephthalates to Dimethyl Cyclohexane-1,4-Dicarboxylates and the Preparation Thereof(2001)[11] 1344.2.2 A Plasticizer Containing Cyclohexane Multi-carboxylate and its Preparation Method(2006)[12] 1354.2.3 A Catalyst for Preparing Cyclohexane-1,2-Dicarbolxylates(2008)[13] 1364.2.4 A Method for Preparing Cyclohexane-1,2-Dicarboxylates (2008)[14] 1374.2.5 A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1,2-Dicarboxylate(DEHCH)(2009)[15] 1394.2.6 A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1,2-Dicarboxylate(DEHCH)Plasticizer(2011)[16] 1404.2.7 A Method for Preparing Cyclohexane-1,2-Dicarboxylates Using Organic Acid Catalysts(2010)[17] 1414.2.8 A Method for Preparing Cyclohexane-1,2