《高分子物理基础（Fundamental of Polymer Physics）》是高分子材料与工程专业系列的纯英文教材。
內容簡介：
《高分子物理基础（Fundamental of Polymer Physics）》为全英文教材，通过研究聚合物的分子运动，揭示了结构与性能之间的内在联系和基本规律，为聚合物的合成、设计、制备与改性、成型、性能测试和质量控制提供理论依据。本教材系统地介绍了高分子物理的基本概念和理论，并介绍了相关的实际应用案例和各部分的最新进展。本书共分为11章，包括5个部分：①绪论；②高聚物的结构，包括分子量和分布、链结构、聚集态结构、溶液和共混结构；③高聚物的分子运动；④高聚物的性能，包括力学性能和电学性能；⑤聚合物的典型测试和表征方法。
Contents
Contents高分子物理基础Chapter 1Introduction1
1 1The importance of polymer science and engineering1
1 2The task of polymer physics1
1 2 1The main task of polymer physics1
1 2 2Main contents and the requirements of the course2
1 3The definition and the chemical nature of polymers2
1 3 1Introduction2
1 3 2The classification of polymers4
1 3 3Classical polymerization processes7
1 3 4Newer polymers and polymerization processes11
1 4A brief history of the development of polymer science and synthetic polymers12
1 4 1Development of polymer science12
1 4 2Development of synthetic polymers16
1 5Properties and applications of polymers20
1 6Polymer processing22
1 6 1Introduction22
1 6 2Additives and composites22
1 6 3Polymer processing23
Questions25
Reference25
Chapter 2Molecular sizes—the molecular mass and distribution27
2 1Introduction27
2 2Statistical significance of polymer molecular mass28
2 3Characterization methods of polymer molecular mass28
2 4Characterization method of the molecular mass distribution30
2 5Determination of molar masses and distributions33
2 5 1Endgroup Analysis35
2 5 2Osmotic Pressure 36
2 5 3Light Scattering 38
2 5 4Flight Time 46
2 5 5Viscometry 51
2 6Determination Methods of Molecular Mass Distribution54
2 6 1Phase Separation and Fractionation 54
2 6 2Gel Permeation Chromatography 55
Questions59
Reference61
Chapter 3The chain structure of polymers65
3 1Introduction65
3 2Construction66
3 3Configuration68
3 3 1Bonding methods of monomer68
3 3 2Branching70
3 3 3Crosslinking 71
3 3 4Sequential structure of copolymer 72
3 3 5Configuration isomerism of polymer chains 74
3 4Conformation77
3 4 1Size and shape of polymer chain78
3 4 2The shapes of polymer molecules79
3 4 3The internal rotational conformation and flexibility of a polymer chain83
3 4 4The single freely jointed chain90
3 4 5More realistic chainsthe excluded volume effect92
3 4 6Characteristics of polymer chain flexibility94
3 4 7Wormlike chains95
Questions96
Reference97
Chapter 4The condensed structure of polymers98
4 1Introduction98
4 2Forces between polymer molecules99
4 2 1Van der Waals force and hydrogen bond99
4 2 2Cohesive energy and cohesive energy density101
4 3The structure model of amorphous polymer102
4 3 1Three structural models of amorphous state102
4 3 2The macroconformations of polymers103
4 3 3Lamellar stacks104
4 4Crystalline state of polymers105
4 4 1Crystal morphology of crystalline polymers 105
4 4 2Crystallization process of polymer117
4 4 3Structural model of crystalline polymers126
4 5Crystallinity129
4 5 1Definition of crystallinity129
4 5 2Experimental determination of crystallinity130
4 5 3Factors influencing crystallinity133
4 5 4The effect of crystallinity on polymer properties138
4 6Melting and melting point of crystalline polymers142
4 6 1Melting thermodynamic analysis of crystalline polymers142
4 6 2Melting characteristics of crystalline polymers142
4 6 3Influencing factors of polymer melting point144
4 7Orientation state of polymer153
4 7 1Orientation phenomenon of polymer153
4 7 2Orientation mechanism155
4 7 3Degree of orientation and its testing methods156
4 7 4Applications of orientation156
4 8Liquid crystal state of polymer159
4 8 1The structure of polymer liquid crystal159
4 8 2Characteristics of polymer liquid crystals161
4 8 3Application of polymer liquid crystal163
Questions164
Reference165
Chapter 5Polymer solution167
5 1Introduction167
5 2Polymer dissolution process and solvent selection168
5 2 1Characteristics of polymer dissolution processes170
5 2 2Thermodynamic explanation of polymer dissolution process172
5 2 3Selection of polymer solvent176
5 3FloryHuggins polymer solution theory178
5 3 1Mixing entropy（ΔSm)179
5 3 2Heat of mixing181
5 3 3Chemical potential of polymer solution183
5 4Ideal solution of polymer184
5 5Nonideal behavior theory of polymer solutions186
5 5 1FloryKrigbaum dilute solution theory186
5 5 2FloryRehner solution theory189
5 5 3Van′t Hoff dilution theories190
5 6Phase equilibrium and phase separation of polymer solutions191
5 7Scaling concept and scaling law of polymers194
5 8Semidilute polymer solutions195
5 8 1The dilute to semidilute transition196
5 8 2The size of a polymer chain in a semidilute solution197
5 8 3A series drop model of semidilute solution197
5 8 4Osmotic pressure of a semidilute solution198
5 9The influence of temperature and concentration on the size of polymeric
chains in a solution200
5 10Polymer gels200
5 11Polyelectrolyte solution201
5 12Diffusion of polymers in solution203
5 13Viscous motion of flexible polymers in dilute solution205
Questions210
Reference211
Chapter 6Polymer blends212
6 1Introduction212
6 1 1Polymer blends and its category212
6 1 2Types of polymer blends and expression of blends composition212
6 1 3Advantages of polymer blending 213
6 2Preparation methods of polymer blends215
6 3Thermodynamic basis of polymer blends216
6 4Compatibility and compatibilization of polymer blends218
6 4 1Fundamental concept of polymer compatibility218
6 4 2Compatibility prediction219
6 4 3Research methods of compatibility220
6 4 4Methods to enhance compatibility224
6 5Morphology of polymer blends225
6 5 1Types of morphology in polymer blends225
6 5 2Factors influencing the phase morphology of polymer blends231
6 6Phase interfaces of blends234
6 6 1Factors related to polymer surface tension234
6 6 2Interfacial tension of polymerpolymer twophase system236
6 6 3Interface layer and interface action237
6 7Performance of polymer blend systems240
6 7 1Factors affecting blend performance241
6 7 2General relationship between the properties of polymer blends and their components242
6 7 3Mechanical properties of polymer blends248
6 7 4Rheological properties of polymer blends248
6 7 5Glass transition of polymer blend systems251
Questions255
Reference256
Chapter 7Motion of polymer molecules257
7 1Introduction257
7 2Characteristics of thermal motion of polymer molecules257
7 3Polymer molecular motion and mechanical state260
7 3 1Mechanical state transition of amorphous polymers260
7 3 2Secondary relaxation transition263
7 4The glass transition of polymers263
7 4 1Evidence of the glass transition in polymers263
7 4 2The theory of glass transition in polymers265
7 4 3Measurement of Tg269
7 4 4Factors affecting the Tg273
7 5Viscous flow284
7 5 1The movement of chains during polymer viscosity flow284
7 5 2The snakelike motion of polymer chains and the pipe model in viscoelastic flow285
7 5 3Factors of influence on viscosity flow temperature287
7 5 4Factors affecting the viscosity of polymer melt292
Questions297
Reference299
Chapter 8Mechanical properties of polymersPart I：Tensile，Yield，
Break and Strength300
8 1Introduction300
8 2Basic physical quantities and mechanical performance parameters301
8 3Tensile behavior of polymers309
8 3 1Stressstrain curves of glassy state polymers313
8 3 2The stressstrain curve of crystalline and semicrystalline polymers316
8 3 3Tensile behavior of hardelastic polymers 317
8 3 4Plasticrubber transition by strain319
8 4Yield of polymers321
8 5Fracture theory and theoretical strength of polymers322
8 5 1Fracture theory322
8 5 2Theoretical strength of polymers327
8 6Factors that influence the actual strength of polymers329
8 6 1Effects of structural factors of polymers329
8 6 2Effects of crystallization and orientation330
8 6 3Effects of stress concentration331
8 6 4Effects of plasticizers333
8 6 5Effects of fillers333
8 6 6Effects of copolymerization and blending337
8 6 7The influence of external force acting speed and temperature338
Questions339
Reference341
Chapter 9Mechanical properties of polymersPart Ⅱ：High elasticity and
viscoelasticity342
9 1Introduction342
9 2Physical properties of hyperelastic polymers343
9 2 1The phenomenology of rubber elasticity343
9 2 2Characteristics of hyperelasticity349
9 2 3The thermodynamic analysis of rubber elasticity354
9 2 4The statistical theory of rubber elasticity355
9 3Swelling of crosslinked networks and the ultimate properties of rubber365
9 4Mechanical relaxation of polymersviscoelasticity366
9 4 1Mechanical relaxation phenomenon of polymers366
9 4 2Mechanical models of viscoelasticity369
9 5The relationship between viscoelasticity and time，temperaturetime
equivalence principle374
9 6Boltzmann superposition principle376
9 7Experimental methods for studying viscoelastic behaviour378
9 7 1Transient measurements378
9 7 2Dynamic measurementsthe complex modulus and compliance379
9 7 3Dynamic measurements；examples380
9 8Relaxation transformation and molecular mechanism of polymers387
Questions394
Reference397
Chapter 10Other properties of polymers398
10 1Introduction398
10 2Electrical properties of polymers398
10 2 1Dielectric properties of polymers398
10 2 2Polymer conductivity409
10 2 3Electrostatic phenomena in polymers410
10 2 4Other electrical properties of polymers411
10 3Optical properties of polymers412
10 4Permeability of polymers413
10 4 1Definition413
10 4 2Gas permeation theory413
10 4 3Major factors affecting gas permeability414
10 5Surface and interface properties of polymers415
10 5 1The bonding properties of the interface416
10 5 2Performance of Polymer Adhesives417
10 5 3Surface modification417
10 6Thermal Performance418
10 6 1Thermal resistance performance418
10 6 2Thermal decomposition of polymers422
10 6 3Thermal conductivity of polymer425
10 6 4Thermal expansion property425
10 6 5Specific heat（heat capacity)427
10 7Biocompatibility of polymer materials427
10 7 1Special requirements for bone cement427
10 7 2Polymeric materials for blood contact428
Questions429
Reference429
Chapter 11Analyzing and characterizing methods of polymers432
11 1Introduction432
11 2Infrared and Raman spectroscopy432
11 2 1Infrared Spectroscopy 432
11 2 2Laser Raman spectroscopy 435
11 3Mass spectrometry437
11 3 1The basic principle of mass spectrometry 437
11 3 2The application of mass spectrometry438
11 4Nuclear magnetic resonance method439
11 4 1Chemical shift440
11 4 2Fourier transform nuclear magnetic technology 442
11 4 3Spinspin coupling，dipole decoupling and cross polarization442
11 4 4Magic Angle Spinning443
11 4 5Application of NMR in the study of polymer chain structure444
11 4 6Nuclear magnetic resonance microscopic imaging technology 445
11 5Smallangle laser scattering method446
11 5 1The principle of measuring spherulite size by small angle laser scattering method 446
11 5 2Study on phase separation process by small angle laser scattering method448
11 6Dynamic light scattering method449
11 6 1Data processing of dynamic light scattering 452
11 6 2Application of dynamic light scattering 453
11 7Xray diffraction and small angle Xray scattering454
11 7 1Xray diffraction study of crystal structure 454
11 7 2Xray small angle scattering method 457
11 8Small angle neutron scattering method460
11 9Laser confocal microscope463
11 10Electron microscope464
11 10 1The construction principle of transmission electron microscope 464
11 10 2Experimental method of transmission electron microscope 465
11 10 3The application of transmission electron microscopy 467
11 10 4Scanning electron microscope468
11 11Atomic force microscope（AFM)471
11 11 1The working principle and device composition of AFM471
11 11 2Working mode of AFM 473
11 11 3Application of AFM475
11 12Thermal analysis of polymersDSC and DTA476
11 13Thermal stability analysis of polymer479
Questions480
Reference481
內容試閱：
The major of Materials Science and Engineering at Xihua University originated from the Foundry Technology and Equipment set in 1978 by Sichuan Agricultural Machinery college，which is the predecessor of Xihua university In 1984，the Metal Materials Department of Sichuan Institute of Technology was established，and in 1998，it was renamed as the Materials Science and Engineering Department of Sichuan Institute of Technology Now，Materials Science and Engineering has become a characteristic major in Sichuan Province，a pilot program for the Sichuan Excellent Engineer Training Program，and a national firstclass program The major of Materials Science and Engineering has passed the National Engineering Education Professional Certification in 2021 The bilingual course of Polymer Physics has always been one of the important foundational courses in this major，receiving consistent attention and support from，colleges and majors In 2007，this course was developed into a highquality course In 2012，this course was approved as a level/provincial bilingual course Since 2017，the practice of blended teaching methods has been carried out In 2020，the course was approved as a firstclass and flipped course at Xihua University In 2021， ”Polymer Physics” was rated as a provinciallevel mixed online and offline firstclass course in Sichuan province
With the reform and opening up of China and the prosperity of the polymer industry，the demand for composite technical talents with both professional knowledge and foreign language communication and expression abilities is increasing day by day College English courses undertake the education of students′ general English，while the cultivation of professional English abilities relies more on professional teachers and courses Therefore，in addition to offering an independent course of Materials Science and Engineering Professional English，this major conducts bilingual teaching in both Chinese and English during the teaching process of the basic courses of ”Polymer Physics” This not only helps to improve students′ practical application of English，but also helps to expand their knowledge，broaden their international perspective，and promote their integration with the international community The polymer science and engineering courses in universities mainly include polymer chemistry，polymer physics，principles and techniques of polymer molding and processing，polymer blends，and polymer analysis methods This course is mainly intended for interested graduate students，senior undergraduate/junior college students，and can also serve as a reference for technical personnel engaged in polymer research and production Polymer physics is usually a basic course for polymer majors to study in universities，with certain interdisciplinary characteristics Through the study of this course，students should master the basic concepts，theories and methods of polymer physics，master the relationships between the structure and performance of polymers，understand the role of molecular motion in connecting structure and performance，and be able to solve theoretical and practical problems in the polymer industry based on the knowledge system of ”structure performance processing application” In the process of solving problems，factors such as law，safety，efficiency and cost，and environmental health can be fully considered The course ultimately provides support for cultivating specialized talents with critical thinking ability，innovation/entrepreneurship spirit，international perspective，patriotism，and professional ethics that can adapt to the needs of local economic construction and development
……
購物車/收銀台(
0
) | 在線留言板
| 付款方式
| 運費計算
| 聯絡我們
| 幫助中心 |
加入書簽
HOME
新書上架
